A Highly Active Hydroformylation Catalyst Using a Self‐Assembling Bis‐N‐Pyrrolyl Phosphine Ligand
نویسندگان
چکیده
Herein we report an improved self-assembling phosphorus ligand based on hydrogen bonding between pyridone/hydroxypyridine in the backbone. The N-pyrrolyl substituents significantly improve π-backbonding properties of ligand. Rhodium, iridium and platinum complexes were prepared analyzed by NMR spectroscopy x-ray crystal structure analysis. A catalyst this showed very high catalytic activity linear regioselectivity rhodium-catalyzed hydroformylation 1-octene. same was applied regioselective iridium-catalyzed
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ژورنال
عنوان ژورنال: Asian Journal of Organic Chemistry
سال: 2023
ISSN: ['2193-5815', '2193-5807']
DOI: https://doi.org/10.1002/ajoc.202300244